1.1 Reaction Kinetics:-
Rate laws - rates constant for first, second, third
and zero order reaction - Half life period - Arrehenius
theory - collission theory - Absolute reaction rate
theory - ionic reaction - salt effect - catalysis -
Laws of photo chemistry, quantum efficiency - photo
physical processes of electronic excited molecules.
1.2 Chemical Equilibrium:-
partial molar quantities, gibbs - Dubem equation, Equilibrium
constant - temperature dependence of equilibrium constant
- phase rule and its applicantions to two and three
components systems.
1.3 Solid State:-
Gystal systems - designation of crystal faces, lattice
structure and unit cell - law of rational indices -
Bragg's law and x rays diffractrion by crystals - schottky
and Frenkel defects - Electrical properties - Insulators
and semiconductors - band theory of solids.
1.4 Electrochemistry:-
Types of Reversible electrodes - Nearnst equation -
calculation of thermo dynamic quantities of cell reactions
- everpotential and hydrogen over voltage - Determination
of pka of acids by potentiometric methods - Kohlarash's
law - ostwald's dilution law - Debye - Huckel ensager
equation for Strong electrolytes - (no derivation required)
- Primary and Secondary fuelcells - corrosion and prevention.
1.5 Structure and
Bonding:-
Electronic configuration of atoms, Torm symbols and
periodic properties of elements, Ionic radii, ionisation
potential electron affinity, electronegativity, concept
of Hybridization molecular orbitals and electronic configuration
of homonuclear and hetero nuclear diatonic molecules,
shapes of polyatomic molecules VSEPR theory, symmetry
elements and point groups for simple molecules, Bond
lengths, Bond angles, bound order and bond energies
Types of chemical bound (weak and strong) inter molecular
forces, structure of simple ionic and covalent bonds
- lattic energy.
1.6 Acids and Bases:-
Bronsted and Lowis acids and bases - pH and pKa acid
- base concept in non - aqueous media - HSAB concept
- Buffer Solutions. Redox Reactions:- Oxidation numbers,
Redox potential, Electro chemical series - Redox indicators.
1.7 Chemistry of
Non - transition elements:-
General characteristics, structure and reaction of simple
compounds - boranes - silicates Oxoacids of N,P,S and
halagens - xenoncompounds - inter halegens, Pseudehalides
and noble gas compounds.
1.8 IUPAC Nomonclature
of simple organic and Inorganic compounds.
1.9 Organic reaction
mechanism:-
General methods (Kinetic and non Kinetic) of study of
reaction mechanisms SN1, SN2 mechanisms - addition substitution,
elimination and rearrangements -free radical mechanism
- aromatic substitution - formation and stability of
reactive intermediate (Carbocations, Carbanion's free
radicals, nitrates and benzynes) - Polar effects - Hammett's
equation and it modification.
1.10 Chemistry of
important organic reaction:-
Aldol condensation - Claisen condensation - perkin reaction
- cannizare reaction - Fridel craft reaction - Favorski
reaction - Strok enamine reaction - Michnel addition
- Baeyer - villager reaction - Chichibabin reaction
pericyclic reactions - classification and examples -
woodward and Hoffmann rules - use of Os O4, NBS, diborane,
NaBH4, LiA1H4 in organic Synthosis.
PAPER - II
2.1 Quantum Chemistry:-
Planck's quantum theory wave - particle duality, uncertainty
principle, operators and commutation relations, postulates
of quantum mechanics, schrodinger wave equation, particlein
one dimensional box and three dimensional box - harmonic
oscillator, rigid retator and hydrogen atom, angular
momentum, spin - orbig coupling.
2.2 Classical thermodynamics
and elements of statistical thermo dynamics:-
First law of thermodynamics:- heat capacity - isothermal
adiabatic processes - Thermo chemical laws - Kircheff's
equation second law of thermodynamics, entropy, in reversible
and irreversible processes - Gibe's free energy and
Helmholtz free energy - Third law of thermodynamics,
calculation of entropy, exception to third law - Mathematical
and thermo dynamic Probability - Thermodynamic variables
interms of partition functions, various types of partition
functions, vibrational and electronic parition functions
for atomic and molecular gases - sackur - Tetrdo equation
- free energy and euthalphy funciton.
2.3 Spectroscopy:-
Rotational spectra of diatomic molecules - Isotopic
substitution and retational constants - vibrations spectra
of linear symmetric, linear asymmetric and bent tri
atomic molecules - electronic spectra - selection rules
- nuclear magnetic resonance - chemical shifts - spin
- spin coupling - election spin resonance and hyperfine
splitting theoretical principles of mass spectroscopy.
2.4 application's
of UV, IR, NMR, ESR and mass spectroscopy for structural
elucidation of organic compounds, inorganic complexos
and free radicals.
2.5 Chemistry of
Co-ordination Compounds:-
structural aspects, isomorism - octahedral and tetrahedral,
crystal - splitting of orbitals - CFSE - magnetism and
colour of transition metal ions - charge transfer spectra
- crystal field theory and ligand field theory - complexes
of II accepter ligands - stereo chemistry of inorganic
co-ordination compounds.
2.6 Chemistry of
lathanidos and actinides:-
Electronic configuration - Separation techniques -exidation
states magnetic and spectroscopic properties - use of
lanthanide compounds as shift reagents.
2.7 Organemetallic
compounds and bio inorganic chemistry:-
Metal carbonyls, Metal nitrosyls, metal alkyl, alkones
and arone compounds - organic metallic compounds in
catalysis - Chemistry of porphyrins - chlorophyll homeglobin,
myoglobin, ferrodexin, rubredoxin, and cytochremes.
2.8 Stereochemistry:-
Elements of symmetry - optical and goemetric isomerism
E. Z and R.S notation's - Conformational analysis simple
cyclic and acyclic systems - Effects of conformation
on reactivity in acyclic compounds and cyclohexanes.
2.9 Carbohydrates:-
Classification - configuration and general reactions
of monosacharides - Chemistry of glucose, fructose,
Surcose and Maltose, Important compounds in chemistry
- Dyes - aze, triphenylmethane, and phthalein groups
- indige - alizarin vitamins, hormones - antibiotics
- proteins. Polymers: Preperation and uses of polythylene,
poly butylene PVC, Nylon - Ziegler - Natta catalysts
- Inorganic Polymers such as silicones, Borazines and
phosphonitrilic compounds
2.10 Instrumental
methods of analysis:-
Adsorption, partition chromate graphy - Gas chromatography
- HPLC - Solvent extraction and ion exchange methods
- atomic absorption spectroscopy - Eletroanalytical
techniques voltammetry, cyclic voltammetry, polarogaphy,
amperonmetry, Coulometry and conductometry, ion - Selective
elctrodes- TGA, DTA and DSC.
|
