UNIT I
PHYSICAL CHEMISTRY:-
a) Gas law and Kinetic Theory:- Ideal gas equation -
Deviation from ideal behaviour - vander waals equation
for real gases - Molecular velocities - the Maxwell's
distribution of molecular velocities.
b) Solid State:- Crystal systems - Bravaislattice -
Unit Cell - Miller Indices - Symmetry elements in crystals
- Bragg's equation - Radius ratio's and packing in crystals.
c) Thermodynamics:- Intensive and extensive variables
- First law of thermodynamics - CP and CV relation -
Hess's law of constant heat summation - Kirchoff's equation
- Second law of thermodynamics - Carnot theorem - entropy
and probability - Free energy and Chemical equilibrium
- third law - Gibb's and Helmholtz functions.
UNIT II
d) Chemical Kinetics:- Rate laws - rate constant - order
and molecularity of reactions - Arrhenius theory - collision
theory and Transition state theory - catalysis.
e) Electro-Chemistry:- Types of reversible electrodes
- Nernst equation - reference electrode and standard
hydrogen electrode - computation of cell e.m.f. calculations
of thermodynamic quantities of cell reactions (DG, DH,
DS and K) - Over potential and hydrogen over voltage
- Arrhenius theory - Debye 'Huckel equation - Kohliraush's
law - Ostwald's dilution law - Determination of PH and
Pka of acids by potentio metric methods.
UNIT III
f) Chemical spectroscopy:- Elementary ideas of microwave,
infrared, Raman, uv, NMR, ESR and Mass spectroscopy.
UNIT IV
g) Colloids and surface Chemistry:- Classification -
preparation purification - properties - Tyndall effect
- Gels - Emulsions Absorption - Langmur isotherms -
Heterogeneous catalysis.
h) Physical properties and Chemical constitution:- Surface
tension - parachor and its application to structural
problems - Dipolemoment - applications of dipolemoment
measurements to structural studies of simple inorganic
and organic molecules - magnetic properties of matter,
diamagnetism, paramagnetism, ferromagnetism and anti-ferromagnetism
- Applications to structural problems.
UNIT V
INORGANIC CHEMISTRY:-
i)
Periodic classification:- Classification based on electronic
configuration - periodic properties - atomic and ionic
radii, ionisation potential, electron affinity and electronegativity
along periods and groups.
j) Chemical bond:- Lattice energy - VSEPR Theory and
its applications - partial ionic character from electronegativity
- Fajan's Rules.
k) Compounds of Boron:- Electron deficient nature of
boron compounds - preparation and properties of halides
and nitrates of boron - diborane - Borazine.
UNIT VI
l) LANTHANIDES AND ACTINIDES:-
Electronic configuration oxidation state, magnetic properties
and complexation behaviour - comparison of lanthanides
and actinides and their position in the periodic table.
m) Fertilisers:- Ammonium nitrate, ammonium phosphate,
Superphosphate and Diammonium Phosphate, NPK fertilisers.
n) Nuclear Chemistry:- Nuclear stability, - n/p ratio
- isotopes, isobars and isotones Nuclear reactions Spellation
- Nuclear fission and fusion - uses of nuclear energy
- applications of tracers in industry, medicine, agriculture.
UNIT VII
o) Co-ordination Chemistry:- Nomenclature - theories
of co-ordination compounds - werner, valence bond, crystal
field molecular orbital and ligand field theories -
Effective atomic number - isomerism - Metal Carbonyls
of iron and Nickel.
p) Analytical Chemistry:- i) Principles of volumetric
analysis - gravimetric analysis - separation and purification
techniques.
UNIT VIII
ORGANIC CHEMISTRY:-
q) Types of reactions:- Nucleophilic, electrophilic,
free radicals, addition and elimination reactions.
r) Electron displacement effects:- Inductive, inductometric,
electromeric, mesomeric, resonance, hyperconjugation
and steric effects.
UNIT IX
s) Nature of Bonding:- Hybridisation (Sp, Sp2 &
Sp3) and Geometry of molecule - cleavage of bonds -
homolytic and heterolytic fission of carbon - carbonbonds
- Reaction intermediates - free radicals, carbocations
and carbonions - their stability.
t) Stereo Chemistry:- Optical isomerism and Geometrical
isomerism - chirality - optical isomerism of lactic
and tartaric acid - Racemisation - Resolution - Asymmetric
synthesis - walden inversion - cis and trans isomerism
of maleic and fumeric acids - R-S-Notations - conformational
analysis of cyclohexane.
UNIT X
u) Dyes:- Classification and Properties of dyes - methyl
orange, cangored, malachite green, fluorenscein and
indigo.
v) Carbon hydrates:- Classification and reactions -
Glucose, Fructose, Sucrose and lactose - structure of
glucose and fructose.
w) Aromatic Substitution:- Mechanism of nitration, Halogenation,
sulphoration and Friedel Crafts reaction - Orientation
effects - nucleophilic substitution - Benzyne mechanism.
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